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- W2023129092 abstract "2,2,4-Trimethylpent-3-en-1-ol (Me2C:CH·CMe2·CH2·OH) reacts with palladium(II) chloride to give π-enyl complexes, i.e.{[(CH2·CMe·CH)·CMe2·CH2·OAc]PdCl}2 in aqueous acetic acid and {[(CH2·CMe·CH)·CMe2·CH2·OH]PdCl}2 in dimethylformamide. No interaction between the palladium and acetate or hydroxy-functions is observed. Reaction with [Rh(CO)2Cl]2 in benzene gives the olefin complex [(Me2C:CH·CMe2·CH2·OH)Rh(CO)Cl]2 in which the hydroxy-function is also co-ordinated to the metal. With platinum(II) chloride in dimethylformamide the alcohol yields an olefin complex [Me2C:CH·CMe2·CH2·O·PtCl]2 which contains a Pt–O covalent bond. N.m.r. and i.r. data are given to support the structures proposed." @default.
- W2023129092 created "2016-06-24" @default.
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- W2023129092 date "1971-01-01" @default.
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- W2023129092 title "Rhodium, palladium, and platinum complexes formed from 2,2,4-trimethylpent-3-en-1-ol" @default.
- W2023129092 doi "https://doi.org/10.1039/j19710003592" @default.
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