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• W2023129199 abstract "The reaction between cis-[Pt(C6F5)2(PPh2H)2], [Pt(norbornene)3], and PPh3 (1:1:1) results in the formation of the Pt(II) derivatives [(C6F5)2Pt(μ-PPh2)(μ-H)Pt(PPh2H)(PPh3)] (1) and [{(C6F5)(PPh3)Pt(μ-PPh2)(μ-H)}2Pt] (2). For the molar ratio 1:1:2 the reaction proceeds with formation of the Pt(I) derivative [(C6F5)(PPh3)Pt(μ-PPh2)Pt(PPh3)2] (3) and the Pt(II) derivatives [(C6F5)2Pt(μ-PPh2)(μ-H)Pt(PPh3)2] (4) and [(C6F5)(PPh3)Pt(μ-PPh2)2Pt(H)(PPh3)] (5). The structures of complexes 2, 3, and 5 have been established by X-ray diffraction. Spectroscopic (IR and NMR) data are also given." @default.
• W2023129199 created "2016-06-24" @default.
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• W2023129199 date "2001-02-01" @default.
• W2023129199 modified "2023-10-03" @default.
• W2023129199 title "Reactivity of a Secondary Phosphine Platinum(II) Complex with [Pt(norbornene)₃] and PPh₃. Synthesis of New Single Phosphido-Bridged Derivatives of Platinum(I) and Phosphido-Bridged Platinum(II) Hydrides^," @default.
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• W2023129199 doi "https://doi.org/10.1021/om0007973" @default.
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