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• W2023132812 abstract "Photoemission measurements reveal energy level shifts toward the Fermi level when a strong electron acceptor (tetrafluoro-tetracyanoquinodimethane, F4-TCNQ) is deposited on pristine layers of 4,4′,4″-tris(N,N-diphenyl-amino)triphenylamine (TDATA) or 4,4′-bis(N-carbazolyl)biphenyl (CBP). The shifts of the TDATA and CBP energy levels toward the Fermi level of the Au substrate could, in principle, arise from p-type doping of the intrinsic organic layers. While this indeed takes place in TDATA, doping of CBP by F4-TCNQ, i.e., charge transfer complex formation, does not occur. The shifts observed in CBP arise from the diffusion of F4-TCNQ toward the Au substrate, which modifies the buried metal surface potential, leading to a realignment of the energy levels of the organic overlayer." @default.
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• W2023132812 date "2009-08-31" @default.
• W2023132812 modified "2023-10-18" @default.
• W2023132812 title "Interdiffusion of molecular acceptors through organic layers to metal substrates mimics doping-related energy level shifts" @default.
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• W2023132812 doi "https://doi.org/10.1063/1.3213547" @default.
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