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- W2023132861 abstract "The polymorphic relationship between optically active (R)- and for racemic (RS)-forms of 1,2-distearin and 1,2-dipalmitin were studied by X-ray diffraction, infrared spectrum, and the thermal analysis. These glycerides have two crystalline forms, α and β, wherein α is metastable and β is stable under ordinary conditions. The α→β transformation for the (RS)-1,2-distearin crystal was extremely slow as compared with that for the (R)-form crystal, implying that the β-form crystal of (RS)-1,2-distearin is an eutectic mixture of small (R)- and (S)-crystals while the α-form crystal of (RS)-1,2-distearin is composed of a replacement type solid solution of (R)- and (S)-1,2-distearin molecules. Almost the same results were obtained with 1,2-dipalmitin, for which the rate of α→β transformation is higher than that for the 1,2-distarin, probably because of a higher mobility of this compound." @default.
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- W2023132861 date "1984-04-01" @default.
- W2023132861 modified "2023-10-16" @default.
- W2023132861 title "Optically Active and Racemic Glycerides. II. Thermodynamic Studies on the Polymorphic Transition of (<i>R</i>)- and (<i>RS</i>)-1,2-Diglycerides" @default.
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- W2023132861 doi "https://doi.org/10.1246/bcsj.57.956" @default.
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