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- W2023134567 abstract "The reaction of triphenylsilyl chloride with 2-propanol in CCl 4 has been reinvestigated and a mechanism proposed. The HCl produced in the reaction is catalytic. The rate of the uncatalyzed reaction, as determined by extrapolations to zero time, increases more rapidly with 2-propanol concentration than would be required for an order of one in the alcohol. The rate of the HCl-catalyzed path is independent of the 2-propanol concentration in the range studied (5 to 15 volume %) but first order in the HCl concentration, suggesting that the reactive alcohol species in this case is of the form ROH … ClH." @default.
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- W2023134567 date "1969-04-15" @default.
- W2023134567 modified "2023-09-25" @default.
- W2023134567 title "Nucleophilic substitution at silicon: the reaction of triphenylsilyl chloride with 2-propanol in CCl4" @default.
- W2023134567 doi "https://doi.org/10.1139/v69-210" @default.
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