Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023137069> ?p ?o ?g. }
- W2023137069 endingPage "950" @default.
- W2023137069 startingPage "942" @default.
- W2023137069 abstract "The tautomerization of salicylate anion in the presence of Al(III) in ethanol was studied by UV−visible absorption spectroscopy and fluorescence spectroscopy, anisotropy, and lifetime measurements from 100 to 298 K. Complexation with Al(III) causes an equilibrium shift from the normal form of the salicylate anion toward the tautomer form, demonstrating that the presence of a highly charged cation, Al(III), stabilizes the tautomer form of salicylate. Spectra and fluorescence lifetimes of salicylate and other salicyl derivatives in the presence of Al(III) reveal three types of Al(III)−salicylate complexes. In type I complexes, salicylate binds to Al(III) through the carboxylate group, preserving the intramolecular hydrogen bond between the carbonyl oxygen and the phenol group, as indicated by the largely Stokes-shifted fluorescence emission following an excited state proton transfer process. In type II complexes, salicylate binds to Al(III) through the carboxylate group, but the phenol proton is oriented aw..." @default.
- W2023137069 created "2016-06-24" @default.
- W2023137069 creator A5033952314 @default.
- W2023137069 creator A5035348848 @default.
- W2023137069 creator A5055289653 @default.
- W2023137069 creator A5062919883 @default.
- W2023137069 creator A5078927779 @default.
- W2023137069 creator A5084384796 @default.
- W2023137069 date "2001-01-16" @default.
- W2023137069 modified "2023-09-26" @default.
- W2023137069 title "Ground-State Proton Transfer Tautomer of Al(III)−Salicylate Complexes in Ethanol Solution" @default.
- W2023137069 cites W1491712786 @default.
- W2023137069 cites W1964022336 @default.
- W2023137069 cites W1973818153 @default.
- W2023137069 cites W1977331002 @default.
- W2023137069 cites W1981554467 @default.
- W2023137069 cites W1985650179 @default.
- W2023137069 cites W1998829420 @default.
- W2023137069 cites W1999210053 @default.
- W2023137069 cites W1999496898 @default.
- W2023137069 cites W2001080208 @default.
- W2023137069 cites W2007849368 @default.
- W2023137069 cites W2009033334 @default.
- W2023137069 cites W2009627356 @default.
- W2023137069 cites W2009718533 @default.
- W2023137069 cites W2010220806 @default.
- W2023137069 cites W2011092379 @default.
- W2023137069 cites W2017738297 @default.
- W2023137069 cites W2024624698 @default.
- W2023137069 cites W2028873366 @default.
- W2023137069 cites W2040061410 @default.
- W2023137069 cites W2040120107 @default.
- W2023137069 cites W2047565413 @default.
- W2023137069 cites W2052148486 @default.
- W2023137069 cites W2054712369 @default.
- W2023137069 cites W2058596883 @default.
- W2023137069 cites W2063543784 @default.
- W2023137069 cites W2067221072 @default.
- W2023137069 cites W2074765280 @default.
- W2023137069 cites W2079521213 @default.
- W2023137069 cites W2082445608 @default.
- W2023137069 cites W2084264930 @default.
- W2023137069 cites W2087472937 @default.
- W2023137069 cites W2089156538 @default.
- W2023137069 cites W2101086827 @default.
- W2023137069 cites W2114484210 @default.
- W2023137069 cites W2142692102 @default.
- W2023137069 cites W2313985761 @default.
- W2023137069 cites W2346316616 @default.
- W2023137069 cites W2950838305 @default.
- W2023137069 cites W3004928379 @default.
- W2023137069 cites W3137995347 @default.
- W2023137069 cites W3139179273 @default.
- W2023137069 cites W4245528020 @default.
- W2023137069 cites W4246079309 @default.
- W2023137069 doi "https://doi.org/10.1021/jp002844a" @default.
- W2023137069 hasPublicationYear "2001" @default.
- W2023137069 type Work @default.
- W2023137069 sameAs 2023137069 @default.
- W2023137069 citedByCount "10" @default.
- W2023137069 countsByYear W20231370692014 @default.
- W2023137069 countsByYear W20231370692015 @default.
- W2023137069 countsByYear W20231370692017 @default.
- W2023137069 countsByYear W20231370692019 @default.
- W2023137069 countsByYear W20231370692020 @default.
- W2023137069 crossrefType "journal-article" @default.
- W2023137069 hasAuthorship W2023137069A5033952314 @default.
- W2023137069 hasAuthorship W2023137069A5035348848 @default.
- W2023137069 hasAuthorship W2023137069A5055289653 @default.
- W2023137069 hasAuthorship W2023137069A5062919883 @default.
- W2023137069 hasAuthorship W2023137069A5078927779 @default.
- W2023137069 hasAuthorship W2023137069A5084384796 @default.
- W2023137069 hasConcept C111233374 @default.
- W2023137069 hasConcept C121332964 @default.
- W2023137069 hasConcept C147597530 @default.
- W2023137069 hasConcept C155647269 @default.
- W2023137069 hasConcept C178790620 @default.
- W2023137069 hasConcept C184779094 @default.
- W2023137069 hasConcept C185592680 @default.
- W2023137069 hasConcept C2780161600 @default.
- W2023137069 hasConcept C54516573 @default.
- W2023137069 hasConcept C62520636 @default.
- W2023137069 hasConcept C69523127 @default.
- W2023137069 hasConcept C75473681 @default.
- W2023137069 hasConceptScore W2023137069C111233374 @default.
- W2023137069 hasConceptScore W2023137069C121332964 @default.
- W2023137069 hasConceptScore W2023137069C147597530 @default.
- W2023137069 hasConceptScore W2023137069C155647269 @default.
- W2023137069 hasConceptScore W2023137069C178790620 @default.
- W2023137069 hasConceptScore W2023137069C184779094 @default.
- W2023137069 hasConceptScore W2023137069C185592680 @default.
- W2023137069 hasConceptScore W2023137069C2780161600 @default.
- W2023137069 hasConceptScore W2023137069C54516573 @default.
- W2023137069 hasConceptScore W2023137069C62520636 @default.
- W2023137069 hasConceptScore W2023137069C69523127 @default.
- W2023137069 hasConceptScore W2023137069C75473681 @default.
- W2023137069 hasIssue "5" @default.
- W2023137069 hasLocation W20231370691 @default.