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- W2023137497 abstract "A novel series of highly similar and comparable metal-free organic dyes have been designed and synthesized for dye-sensitized solar cells (DSSCs). The end-capped groups, namely, diphenylethylene, triphenylethylene, and tetraphenylethylene, have significant effects on the performance of DSSCs. The DSSC based on a triphenylethylene end-capped dye exhibits the highest power conversion efficiency (η) of 6.29%, whereas that based on a tetraphenylethylene end-capped dye has the highest open-circuit photovoltage (Voc) of 804 mV. The Voc of the DSSCs can be greatly improved upon the incorporation of a twisted non-planar aggregation-induced emission (AIE) moiety in the molecular structure of the dyes. The triphenylethylene group with a moderately twisted non-planar structure is found to be suitable for the improvement of the power conversion efficiency. The dyes exhibit an aggregation-caused emission quenching effect, i.e., the dyes do not emit light after being adsorbed on TiO2 films, although they contain aggregation-induced emission triphenylethylene and tetraphenylethylene moieties." @default.
- W2023137497 created "2016-06-24" @default.
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- W2023137497 date "2012-01-01" @default.
- W2023137497 modified "2023-09-27" @default.
- W2023137497 title "Effect of polyphenyl-substituted ethylene end-capped groups in metal-free organic dyes on performance of dye-sensitized solar cells" @default.
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- W2023137497 doi "https://doi.org/10.1039/c2ra20819a" @default.
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