FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023142095> ?p ?o ?g. }

• W2023142095 endingPage "1807" @default.
• W2023142095 startingPage "1807" @default.
• W2023142095 abstract "We discuss donor–acceptor conjugated polymers where the acceptor moieties are orthogonal to the donor-based backbone direction through the synthesis and study of a new class of materials (including six oligomers and three polymers) based on 4H-cyclopentadithiophene (CPDT) with an imine functionality introduced at the CPDT bridgehead position. Absorption spectroscopy provides information on the influence of structure on the optical properties. We paid special attention to the energies and oscillator strengths of the low-energy transitions and how they correlate with chain length. When the orthogonally conjugated materials are compared to a more traditional polymer, where the donor and acceptor fragments are in series along the backbone direction, fundamental differences in the optical properties are observed. Quantum-mechanical studies of the geometric structure, electronic structure, and excited-state vertical transitions using density functional theory unravel the interplay of structural design and resulting optoelectronic properties. Our findings underline that the magnitude and orientation relative to the backbone long axis of the transition dipole moment is key in designing narrow optical-gap materials with large absorption cross-sections and oscillator strengths." @default.
• W2023142095 created "2016-06-24" @default.
• W2023142095 creator A5021231690 @default.
• W2023142095 creator A5043085531 @default.
• W2023142095 creator A5051743081 @default.
• W2023142095 creator A5051760228 @default.
• W2023142095 creator A5056847387 @default.
• W2023142095 date "2013-01-01" @default.
• W2023142095 modified "2023-09-23" @default.
• W2023142095 title "Structural dependence of the optical properties of narrow bandgap semiconductors with orthogonal donor–acceptor geometries" @default.
• W2023142095 cites W1657433554 @default.
• W2023142095 cites W1966050391 @default.
• W2023142095 cites W1968427871 @default.
• W2023142095 cites W1968621955 @default.
• W2023142095 cites W1969589741 @default.
• W2023142095 cites W1971599368 @default.
• W2023142095 cites W1971705465 @default.
• W2023142095 cites W1973538890 @default.
• W2023142095 cites W1976968670 @default.
• W2023142095 cites W1977950540 @default.
• W2023142095 cites W1980197072 @default.
• W2023142095 cites W1980216394 @default.
• W2023142095 cites W1980564784 @default.
• W2023142095 cites W1980913256 @default.
• W2023142095 cites W1981267398 @default.
• W2023142095 cites W1981296117 @default.
• W2023142095 cites W1981546475 @default.
• W2023142095 cites W1981743633 @default.
• W2023142095 cites W1983073834 @default.
• W2023142095 cites W1983733289 @default.
• W2023142095 cites W1989854295 @default.
• W2023142095 cites W1990189209 @default.
• W2023142095 cites W1991617306 @default.
• W2023142095 cites W1991694251 @default.
• W2023142095 cites W1991706820 @default.
• W2023142095 cites W1993239943 @default.
• W2023142095 cites W1994821826 @default.
• W2023142095 cites W1999523984 @default.
• W2023142095 cites W1999614577 @default.
• W2023142095 cites W2000798385 @default.
• W2023142095 cites W2000962574 @default.
• W2023142095 cites W2001177502 @default.
• W2023142095 cites W2005949326 @default.
• W2023142095 cites W2009907387 @default.
• W2023142095 cites W2010007250 @default.
• W2023142095 cites W2011484919 @default.
• W2023142095 cites W2012027621 @default.
• W2023142095 cites W2012299555 @default.
• W2023142095 cites W2013219470 @default.
• W2023142095 cites W2013722112 @default.
• W2023142095 cites W2015240500 @default.
• W2023142095 cites W2015404131 @default.
• W2023142095 cites W2015741875 @default.
• W2023142095 cites W2016088184 @default.
• W2023142095 cites W2016943360 @default.
• W2023142095 cites W2019512570 @default.
• W2023142095 cites W2021001184 @default.
• W2023142095 cites W2022815260 @default.
• W2023142095 cites W2023271753 @default.
• W2023142095 cites W2024062281 @default.
• W2023142095 cites W2024446708 @default.
• W2023142095 cites W2024808438 @default.
• W2023142095 cites W2024897831 @default.
• W2023142095 cites W2026399784 @default.
• W2023142095 cites W2026615074 @default.
• W2023142095 cites W2029263757 @default.
• W2023142095 cites W2030341018 @default.
• W2023142095 cites W2030782971 @default.
• W2023142095 cites W2031537592 @default.
• W2023142095 cites W2032595418 @default.
• W2023142095 cites W2032695513 @default.
• W2023142095 cites W2033085589 @default.
• W2023142095 cites W2033250243 @default.
• W2023142095 cites W2033562953 @default.
• W2023142095 cites W2033990154 @default.
• W2023142095 cites W2034331955 @default.
• W2023142095 cites W2035050939 @default.
• W2023142095 cites W2035094938 @default.
• W2023142095 cites W2040977131 @default.
• W2023142095 cites W2041859004 @default.
• W2023142095 cites W2047525848 @default.
• W2023142095 cites W2050056663 @default.
• W2023142095 cites W2051170830 @default.
• W2023142095 cites W2051241647 @default.
• W2023142095 cites W2053782439 @default.
• W2023142095 cites W2054087038 @default.
• W2023142095 cites W2055331484 @default.
• W2023142095 cites W2055499045 @default.
• W2023142095 cites W2056215645 @default.
• W2023142095 cites W2056544067 @default.
• W2023142095 cites W2057187425 @default.
• W2023142095 cites W2063645939 @default.
• W2023142095 cites W2063671683 @default.
• W2023142095 cites W2064334393 @default.
• W2023142095 cites W2064903145 @default.
• W2023142095 cites W2067011309 @default.
• W2023142095 cites W2067778667 @default.
• W2023142095 cites W2068543651 @default.

• next