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- W2023144101 abstract "Primary aliphatic amines on oxidation with iodosobenzene in CH2Cl2 or H2O yield the corresponding nitriles, while primary cycloalkylamines give the corresponding cyclic ketones. Lactams are obtained by the oxidation of cyclic amines. (S)(−) Nicotine (15) is oxidized to (+)-cotinine (16). The intermediary imine involved in these processes was trapped in the case of piperidine as the α-aminonitrile." @default.
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- W2023144101 date "1988-01-01" @default.
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- W2023144101 title "Hypervalent iodine oxidation of amines using iodosobenzene: Synthesis of nitriles, ketones and lactams" @default.
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- W2023144101 doi "https://doi.org/10.1016/s0040-4039(00)88473-7" @default.
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