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• W2023152529 abstract "The experimental control of silver nanoparticle shape in citric acid solution is rationalized by ab initio calculations. The approximate three-fold symmetry of the acid matches that of Ag(1 1 1) and results in four silver–oxygen bonds. In contrast, citric acid forms only two bonds with Ag(1 0 0) because of the geometry mismatch. Migration of a hydrogen atom within citric acid activates the electrons of the carboxyl oxygens and provides additional binding affinity towards Ag(1 1 1). The preferential binding energy of citric acid to Ag(1 1 1) promotes crystal growth along the Ag(1 0 0) surface." @default.
• W2023152529 created "2016-06-24" @default.
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• W2023152529 date "2008-06-01" @default.
• W2023152529 modified "2023-10-03" @default.
• W2023152529 title "Shape-controlled synthesis of silver nanoparticles: Ab initio study of preferential surface coordination with citric acid" @default.
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• W2023152529 doi "https://doi.org/10.1016/j.cplett.2008.04.046" @default.
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