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- W2023153274 abstract "The use of ortho-chloranil (o-CA) as an electrochromic material requires three conditions to operate properly: (1) the reversibility of the electronic transfer of the reaction ; (2) the formation of a visible-light absorbing charge-transfer complex between o-Ca− and the counterion M+, and (3) the use of an insoluble salt o-CA−M+ as a film adherent to the electrode surface. The behavior of the redox o-CA/o-CA− couple has been investigated in different solvents and in the presence of several alkaline and alkaline earth cations (Mz+). The reversibility of the electron transfer and the formation of an adhesive salt layer on the electrode are strongly related to the counter ion Mz+. The ion-pair formation depends on the solvent and particularly on its weak electron donor character. The best electrochromic properties of o-CA were obtained in 0.1 M NaClO4 acetonitrile solutions." @default.
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- W2023153274 date "1987-09-01" @default.
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- W2023153274 title "Ion-pair effects on the electroreduction and electrochromic properties of ortho-chloranil in dipolar aprotic solvents" @default.
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- W2023153274 doi "https://doi.org/10.1016/0022-0728(87)80207-3" @default.
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