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- W2023155476 abstract "Analysis of 1-octanol–water, cyclohexane–water and chloroform (CHCl3)–water partition coefficients Po–ch–cf allows calculation of molecular lipophilicity patterns, which show that for a given atom log Po–ch–cf is sensitive to the presence of functional groups. Program CDHI does not properly differentiate between non-equivalent atoms. The most abundant single-wall carbon nanotube (SWNT), (10,10), presents a relatively small aqueous solubility and large elementary polarizability, Po–ch–cf and kinetic stability. The SWNT solubility is studied in various solvents, finding a class of non-hydrogen-bonding Lewis bases with good solubility. Solvents group into three classes. The SWNTs in some organic solvents are cationic while in water/Triton X mixture are anionic. Categorized solubility is semiquantitatively correlated with solvent parameters. The coefficient of term β is positive while the ones of ε and V negative. The electron affinity of D-glucopyranoses (D-Glcpn) suggests the formation of colloids of anionic SWNTs in water. Dipole moment for D-Glcpn-linear increases with n until four in agreement with 18-fold helix. The Inz− and SWNT− are proposed to form inclusion complexes with cyclodextrin (CD) and amylose (Amy). Starch, D-Glcp, CD and Amy are proposed as SWNT co-solvents. Guests–hosts are unperturbed. A central channel expansion is suggested." @default.
- W2023155476 created "2016-06-24" @default.
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- W2023155476 date "2011-01-01" @default.
- W2023155476 modified "2023-09-24" @default.
- W2023155476 title "(Co-)solvent selection for single-wall carbon nanotubes: best solvents, acids, superacids and guest–host inclusion complexes" @default.
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- W2023155476 doi "https://doi.org/10.1039/c0nr00922a" @default.
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