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- W2023156305 abstract "Abstract. Reaction of zinc acetate with four different substituted pyrazoles (3,5-dimethyl pyrazole (3,5-Me2PzH), 3,5-di-tert-butyl pyrazole (3,5-tBu2PzH), 3,5-diphenyl pyrazole (3,5-Ph2PzH), and 5-methyl-3-phenyl pyrazole (3-Ph-5-Me-PzH)) followed by treatment with(η6-benzenecarboxylic acid) chromium tricarbonyl afforded the bimetallic zinc-chromium complexes [Zn{(η6-C6H5COO)Cr(CO)3}2(3,5-Me2PzH)2], [Zn{(η6-C6H5COO)Cr(CO)3}2(3,5-tBu2PzH)2], [Zn{(η6-C6H5COO)Cr(CO)3}2(3,5-Ph2PzH)2], and [Zn{η6-C6H5COO)Cr(CO)3}2(3-Ph-5-Me-PzH)2]. The corresponding bimetallic cadmium-chromium complexes [Cd{(η6-C6H5COO)Cr(CO)3}2(3,5-Me2PzH)2] and [Cd{(η6-C6H5COO)Cr(CO)3}2(3,5-tBu2PzH)2] were obtained by using cadmium acetate as starting material. The pyrazole rings and the carboxylate {(η6-C6H5COO)Cr(CO)3}– anion act as monodentate ligand in the zinc complexes, whereas a monodentate and bidentate coordination of the {(η6-C6H5COO)Cr(CO)3}– anion is observed in the cadmium complexes." @default.
- W2023156305 created "2016-06-24" @default.
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- W2023156305 date "2011-09-26" @default.
- W2023156305 modified "2023-09-23" @default.
- W2023156305 title "Synthesis and Structures of Zinc(II) and Cadmium(II) Complexes with (η6-Benzenecarboxylate) Chromium Tricarbonyl and Pyrazole Derivatives" @default.
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- W2023156305 doi "https://doi.org/10.1002/zaac.201100269" @default.
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