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- W2023159401 abstract "Complexes of sulphonated triphenylphosphine with Ru(II) and Rh(I) were immobilized on strongly basic anion exchangers. The heterogenized complexes were successfully applied to the hydrogenation of various olefins in solution and in the gas phase, at 60 °C and 120 °C, respectively, and 0.1 MPa total pressure. Kinetic features of crotonic acid hydrogenation in aqueous solution suggest that the anchored RuCl2(m-SPφ2)2 exerts its catalytic influence via the same molecular pathway as in homogeneous solutions" @default.
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- W2023159401 date "1984-05-01" @default.
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- W2023159401 title "Rhodium(I) and ruthenium(II) complexes of sulphonated triphenylphosphine immobilized on ion-exchange materials" @default.
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- W2023159401 doi "https://doi.org/10.1016/0304-5102(84)85127-5" @default.
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