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- W2023161339 abstract "The structure of the salts ScX3, where X- denotes Cl- or I-, was investigated by using neutron diffraction. On heating ScCl3, a phase transition from the FeCl3-type crystal structure to possibly the YCl3-type crystal structure was observed whereas ScI3 remained in its room temperature FeCl3-type crystal structure up to the melting point. On melting, there is a reduction in the Sc-X coordination number from six to 4.8(2) for ScCl3 and from six to 4.7(2) for ScI3 and the Sc-Cl and Sc-I nearest-neighbour distances in the liquid are 2.48(2) Å and 2.76(2) Å respectively. The measured total structure factors of molten ScCl3 and ScI3 each have a prominent first sharp diffraction peak at a scattering vector value of 0.75(5) Å-1. The results are discussed in the context of those available for several other trivalent metal halide systems which also melt from the closely related YCl3-type and FeCl3-type crystal structures." @default.
- W2023161339 created "2016-06-24" @default.
- W2023161339 creator A5044619719 @default.
- W2023161339 creator A5075782332 @default.
- W2023161339 date "1999-01-01" @default.
- W2023161339 modified "2023-09-23" @default.
- W2023161339 title "Structure of molten ScCl<sub>3</sub>and ScI<sub>3</sub>studied by using neutron diffraction" @default.
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- W2023161339 doi "https://doi.org/10.1088/0953-8984/11/10/004" @default.
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