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- W2023162668 abstract "Irradiation of dichromated polyvinyl alcohol and dichromated polyacrylic acid DC(PVA-PAA) at 365 nm wasinvestigated in order to understand the involvement of the polymeric matrix in the reduction process of the Cr(VI)leading to the formation of the hologram. The photochemical evolution of the matrix was directly correlated to thedisappearance of the absorbing species, chromium(VI). A special attention was paid to the absorption profile of thefilms. Due to the impermeability of the polymer, no oxidation proceeded. The reduction of Cr(VI) into Cr(V) induced theformation of carboxylate species perfectly correlated with the consumption of carboxylic groups. Besides the acido-basicreaction undergone by the carboxylic groups, the reduction of Cr(VI) provoked the cross-linking of the polymer. Eachpolymer appears to play a specific role in the mechanism." @default.
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- W2023162668 date "2004-06-29" @default.
- W2023162668 modified "2023-10-05" @default.
- W2023162668 title "Dichromated photosensitive materials: involvement of the polymeric matrix" @default.
- W2023162668 doi "https://doi.org/10.1117/12.529102" @default.
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