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• W2023163657 abstract "Cu 2 ZnSnS 4 is an ideal candidate absorber material for thin film solar cells with an optimal band-gap for a single junction photovoltaic device of 1.4–1.5 eV, high absorption coefficient (>10 4 cm -1 ), and abundant elemental components. In this paper, Cu 2 ZnSnS 4 nanocrystallines have been successfully synthesized by a hydrothermal method using CuCl, ZnCl 2 , SnCl 4 ·5H 2 O and (NH 2 ) 2 CS as reaction reagents for the first time. The as-grown product was characterized by X-ray powder diffraction, transmission electron microscopy, high-resolution transmission electron microscopy and selected-area electron diffraction. The results confirm that the product was polycrystalline Cu 2 ZnSnS 4 nanoparticles with the diameter of 5–7 nm. The effect of the reaction temperature and time on the formation of the Cu 2 ZnSnS 4 nanocrystallines was discussed. The band-gap of Cu 2 ZnSnS 4 nanocrystallines was estimated to be 1.70 eV via ultraviolet–visible (UV–vis) absorption spectrum of Cu 2 ZnSnS 4 nanocrystallines. Raman spectrum of Cu 2 ZnSnS 4 nanocrystallines had about 8 cm -1 red-shift in comparison with that of the responding bulk counterpart." @default.
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• W2023163657 date "2011-06-01" @default.
• W2023163657 modified "2023-09-30" @default.
• W2023163657 title "Synthesis of Cu₂ZnSnS₄ Nanocrystallines by a Hydrothermal Route" @default.
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• W2023163657 doi "https://doi.org/10.1143/jjap.50.065003" @default.
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