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• W2023165458 abstract "Abstract A series of gold(I) complexes with N‐heterocyclic carbene (NHC) and acetylide ligands, namely [Au(NHC 1 )(C≡CAr)] (NHC 1 =1‐(9‐anthracenylmethyl)‐3‐(n)‐butylimidazol‐2‐ylidene; 1 b – 1 g ), [Au(NHC 2 )(C≡CAr)] (NHC 2 =1,3‐diethylimidazol‐2‐ylidene; 2 b – 2 f ) and [Au(C≡NAr) 2 ] + (C≡NAr=arylisocyanide; 3 a – 3 f ) have been synthesized. At room temperature, most of these gold(I) complexes are emissive in the solid state and in solutions with lifetimes in the nanosecond to submicrosecond regime. The emissions of complexes 1 b – 1 g in solutions are assigned to 1 π–π* excited states of the NHC ligand, while that of 2 b – 2 f and 3 a – 3 f are phosphorescent in nature. The intriguing solvatochromism of complex 3 a was also investigated. Complexes 1 b , 1 d , 3 a , and 3 e aggregate into crystalline nanowires in freshly prepared THF/water dispersions. The X‐ray crystallographic data reveal that 1 b and 1 d possess intermolecular π–π and CH⋅⋅⋅π interactions; while 3 a was found to display intermolecular gold(I)⋅⋅⋅π interactions." @default.
• W2023165458 created "2016-06-24" @default.
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• W2023165458 creator A5070448032 @default.
• W2023165458 date "2010-09-13" @default.
• W2023165458 modified "2023-10-17" @default.
• W2023165458 title "Synthesis, Photophysical Properties, and Molecular Aggregation of Gold(I) Complexes Containing Carbon‐Donor Ligands" @default.
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• W2023165458 doi "https://doi.org/10.1002/asia.201000499" @default.
• W2023165458 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20839277" @default.
• W2023165458 hasPublicationYear "2010" @default.
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