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- W2023168106 abstract "The composition of methylcopper(I) species, prepared from cuprous halides and MeM (M = Li, MgX or Mg1/2) in various ratios, has been studied by means of 1H NMR spectroscopy. Tetrahydrofuran (THF) was used as solvent. Evidence is presented that in the presence of hexamethylphosphoric triamide (HMPT), methylhalocuprates, [MeCuX]M, can be obtained stoichiometrically pure. By means of 1H NMR analysis it could be shown that the complex MeCu[P(OMe)3]3 also exists in solution. The trimethyldicuprate [Me3Cu2]2Mg has only been obtained stoichiometrically pure on starting from MeMgCl and cuprous chloride; it was formed in equilibrium with [Me2Cu]2Mg and [MeCuBr]2Mg when the starting Grignard reagent or the cuprous halide contained bromide. Homocuprates [Me2Cu]M were always obtained in mixtures containing, in addition to the homocuprate, [Me3Cu2]M and MeM when the starting reagent MeM was a Grignard reagent. Attempts to prepare species with another stoichiometry failed when Grignard reagents MeM were used." @default.
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- W2023168106 date "2010-09-02" @default.
- W2023168106 modified "2023-10-09" @default.
- W2023168106 title "The composition of methylcopper(I) species in solution. A 1H NMR study" @default.
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- W2023168106 doi "https://doi.org/10.1002/recl.19831020608" @default.
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