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- W2023172700 abstract "l-Piperazine-2-carboxylic acid derived N-formamides have been developed as highly enantioselective Lewis basic catalysts for the hydrosilylation of N-aryl imines with trichlorosilane. The arene sulfonyl group on N4 was found to be critical for the high enantioselectivity of the catalyst. High isolated yields (up to 99%) and enantioselectivities (up to 97%) were obtained for a broad range of substrates, including aromatic and aliphatic ketimines, particularly those with R2 as relatively bulky alkyl groups." @default.
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- W2023172700 date "2006-06-06" @default.
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- W2023172700 title "<scp>l</scp>-Piperazine-2-carboxylic Acid Derived <i>N</i>-Formamide as a Highly Enantioselective Lewis Basic Catalyst for Hydrosilylation of <i>N</i>-Aryl Imines with an Unprecedented Substrate Profile" @default.
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- W2023172700 doi "https://doi.org/10.1021/ol060984i" @default.
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