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- W2023173792 abstract "Abstract m -Xylene isomerization and disproportionation kinetics have been studied over four zeolite catalysts (ZSM-5, mordenite, SSZ-33 and TNU-9) in a riser simulator reactor over the temperature range of 300–400 °C. The effect of reaction conditions on m -xylene conversion, p -xylene/ o -xylene (P/O) ratios, ratio of isomerization to disproportionation (I/D) products were investigated with the view of comparing the respective performances of the catalysts. Kinetic parameters for the disappearance of m -xylene were determined using catalyst activity decay function based on time-on-stream (TOS). The experimental results show that SSZ-33, TNU-9 and mordenite gave higher m -xylene conversion compared to ZSM-5. Both m -xylene P/O and I/D ratios over the catalysts were found to be in the order: ZSM-5 > TNU-9 > SSZ-33 > mordenite. Apparent activation energy for m -xylene disproportionation reaction was found to decrease in the order: E ZSM-5 > E TNU-9 > E mordenite > E SSZ-33 . The riser simulator and the modeling procedures employed have proved to be very effective as tools in investigating fluidized bed reaction kinetics." @default.
- W2023173792 created "2016-06-24" @default.
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- W2023173792 date "2011-01-01" @default.
- W2023173792 modified "2023-10-17" @default.
- W2023173792 title "Comparison studies of xylene isomerization and disproportionation reactions between SSZ-33, TNU-9, mordenite and ZSM-5 zeolite catalysts" @default.
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- W2023173792 doi "https://doi.org/10.1016/j.cej.2010.11.004" @default.
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