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- W2023174769 abstract "Bien qu'ayant déja été étudié par de nombreaux auteurs, le comportement électrochimique du sélénium, présente encore de nombreaux points obscurs en particular sur électrode de platine. Nous avons dans cette étude montré que la présence d'oxyde de surface, notamment PtO, influait fortement sur ce comportement, ainsi que sur la structure cristallographique des dépots obtenus. Des analyses spectroscopiques ont été effectuées afin d'éclaircir le rôle de cette couche d'oxyde. La présence de cette couche induit la formation de la variété α monoclinique de sélénium, alors que son absence permet le développement de la forme amorphe. Although studied by a lot of authors, the electrochemical behaviour of selenium still presents some ignored points, especially on platinum electrodes. We have shown in this study that the presence of an oxide layer of PtO had a strong influence on this behavior and on the crystallographic structure of the deposits. Spectroscopic measurements have been performed to enlighten the role of this oxide layer. The presence of this oxide layer induces the formation of the α monoclinic variety of selenium, whereas the amorphous variety grows in its absence." @default.
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- W2023174769 date "1986-07-01" @default.
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- W2023174769 title "Électrodéposition et électrodissolution de sélénium sur électrode de platine en milieu neutre" @default.
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- W2023174769 doi "https://doi.org/10.1016/0013-4686(86)85018-6" @default.
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