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- W2023180988 endingPage "4064" @default.
- W2023180988 startingPage "4056" @default.
- W2023180988 abstract "The ability of five imidazol(in)ium-2-carboxylates and dithiocarboxylates bearing cyclohexyl, mesityl, or 2,6-diisopropylphenyl substituents on their nitrogen atoms to act as NHC precursors for in situ catalytic applications was probed in ruthenium-promoted ring-opening metathesis and atom transfer radical polymerizations. Results obtained with 1:2 mixtures of [RuCl2(p-cymene)]2 and NHC·CO2 adducts were in line with those reported previously starting from preformed [RuCl2(p-cymene)(NHC)] complexes, whereas the NHC·CS2 zwitterions were almost completely inactive. To account for this dichotomy, the preparation of preformed ruthenium−arene complexes from [RuCl2(p-cymene)]2 and NHC·CX2 inner salts was thoroughly investigated. As expected, imidazolium-2-carboxylates lost their CO2 moiety and afforded [RuCl2(p-cymene)(NHC)] complexes in high yields, whereas the NHC·CS2 betaines retained their zwitterionic nature and led to cationic complexes of the [RuCl(p-cymene)(NHC·CS2)]PF6 type. These stable, 18-electron sp..." @default.
- W2023180988 created "2016-06-24" @default.
- W2023180988 creator A5004559759 @default.
- W2023180988 creator A5030153568 @default.
- W2023180988 creator A5054555764 @default.
- W2023180988 creator A5068422233 @default.
- W2023180988 date "2009-07-02" @default.
- W2023180988 modified "2023-10-16" @default.
- W2023180988 title "Synthesis and Catalytic Evaluation of Ruthenium−Arene Complexes Generated Using Imidazol(in)ium-2-carboxylates and Dithiocarboxylates" @default.
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- W2023180988 doi "https://doi.org/10.1021/om9002363" @default.
- W2023180988 hasPublicationYear "2009" @default.
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