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- W2023184110 abstract "The asymmetric synthesis of a tetrasubstituted bicyclic guanidine 1 is described. This salt may serve as an oxoanionbinding modul in open-chain artificial receptors. The synthetic key step involves asymmetric alkylation of a Schöllkopf bislactim ether 8a/b to produce after protection/deprotection steps a chiral open-chain triamine 13 which can be cyclized by thiophosgene as a C1-building block to yield the target structure 1. The diastereoselectivity (%de) and enantioselectivity (%ee) of the synthetic pathway exceed 94%." @default.
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- W2023184110 date "1991-06-13" @default.
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- W2023184110 title "Chiral anchor groups for oxoanions: Asymmetric synthesis of tetrasubstituted bicyclic guanidines" @default.
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