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- W2023184943 abstract "The infra-red spectra of gaseous CH3SCCH and CH3SCCD have been examined between 3500 and 300 cm−1. The vibrational assignments are discussed and compared with the iso-electronic species CH3SCN and CD3SCN. All the fundamental vibrations associated with the CH3—[S] group, with the exception of the torsion vibration, have been observed at (species a′) 3012, 2944, 1447, 1322, 982; (species a″) 3017, 1431 and 961 cm−1. A linear correlation is shown to exist between the frequencies of the out-of-plane CH deformation vibration of monosubstituted acetylenes, RCCH (or degenerate vibration in the case where R is axially symmetric) and the CH2 wagging frequency of the corresponding vinyl molecule RCHCH2. The wide range of CH deformation frequencies in these cases (520–680 cm−1) appears to be related to the mesomeric effect of the substituents." @default.
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- W2023184943 date "1967-01-01" @default.
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- W2023184943 title "The infra-red spectra of methyl ethynyl sulphide and methyl ethynyl-d sulphide" @default.
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- W2023184943 doi "https://doi.org/10.1016/0584-8539(67)80217-4" @default.
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