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• W2023185588 abstract "Abstract Novel comb‐type polyphosphazene derivatives with cyclic carbonate groups as the terminal function of oligo(oxyethylene) side chains [CEP] were prepared for the achievement of high ionic conductivity, when they were hybridized with LiCIO 4 , in accordance with increase of permittivity. The relative permittivity of CEP turned out to be extraordinarily high, i.e. 24,6, whereas that of a similar comb‐type polyphosphazene with methyl ether terminal function of side chains was less than 10 at 25°C. The [LiCIO 4 (5)/CEP (95 wt.‐%)] hybrid showed relatively high ionic conductivity of 7,3 · 10 −6 at 25°C and 9,6 · 10 −5 S · cm −1 at 60°C, respectively. From the observation of the temperature dependence of ionic conductivity at 10–60°C, it was revealed that the ionic conduction obeys the Vogel‐Tamman‐Fulcher and Williams‐Landel‐Ferry equations based on the free volume theory." @default.
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• W2023185588 date "1994-06-01" @default.
• W2023185588 modified "2023-10-17" @default.
• W2023185588 title "Ionic conduction in polyphosphazene containing oligo(oxyethylene) side chains with cyclic carbonate as terminal groups" @default.
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• W2023185588 doi "https://doi.org/10.1002/macp.1994.021950604" @default.
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