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• W2023188825 endingPage "5754" @default.
• W2023188825 startingPage "5749" @default.
• W2023188825 abstract "The lamellar morphology of a melt-miscible blend consisting of two crystalline constituents, poly(vinylidene fluoride) (PVDF) and poly(3-hydroxybutyrate) (PHB), has been investigated by small angle X-ray scattering (SAXS). Owing to the proximity of melting points, PVDF and PHB crystallized over essentially the same temperature range, and consequently created a crystalline/crystalline state with the morphology characterized by the spatial arrangement of PVDF and PHB lamellae. Irrespective of the crystallization temperatures (Tc), the SAXS patterns revealed the presences of two lamellar stack (LS) domains, where one contained mainly PVDF lamellae (PVDF LS domain) and the other primarily consisted of PHB lamellae (PHB LS domain). The interlamellar (IL) regions of both LS domains were found to contain mixed amorphous PVDF and PHB. The blends crystallized at higher Tc exhibited smaller SAXS invariants. This observed Tc dependence was connected with the disparity in crystallization kinetics that gave rise to different LS domain sizes at different Tcs." @default.
• W2023188825 created "2016-06-24" @default.
• W2023188825 creator A5032073769 @default.
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• W2023188825 date "2001-06-01" @default.
• W2023188825 modified "2023-10-14" @default.
• W2023188825 title "Crystallization induced microstructure of crystalline/crystalline poly(vinylidenefluoride)/poly(3-hydroxybutyrate) blends probed by small angle X-ray scattering" @default.
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• W2023188825 doi "https://doi.org/10.1016/s0032-3861(01)00072-6" @default.
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