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- W2023192406 abstract "Polymerization of acrylonitrile (AN) initiated by Ce (IV)-diacetone alcohol (DAA) redox system was studied in the presence of V(V). Rate of polymerization was decreased considerably by the addition of small amounts of V(V). Polymerization was not observed either by V(V) alone or by V(V)-DAA redox system. Under the experimental conditions orders with respect to [Ce(IV)], [DAA] and [AN] were found to be 0.5, 0.5 and 1.5 in the absence of V(V) and these changed to 1.0, 1.0 and 2.0 respectively in the presence of V(V). Mutual termination of polymeric radicals in the absence of V(V) becomes linear termination with V(V) in the presence of V(V). A probable mechanism is proposed to explain the results." @default.
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- W2023192406 date "2010-09-01" @default.
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- W2023192406 title "Termination of CE(IV)-Diacetone Alcohol Redox System Initiated Polymerization of Acrylonitrile by V(V): A Kinetic Study" @default.
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- W2023192406 doi "https://doi.org/10.1002/bscb.19840930106" @default.
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