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- W2023194305 abstract "The nitration of tyrosine derivatives with nitrogen monoxide (nitric oxide) occurs only in the presence of dioxygen, and the hypothesized mechanism involves nitrogen dioxide (·NO2). For better understanding of the reaction mechanism, the nitration of model compounds − such as 1- and 2-naphthols and their corresponding 2- and 1-nitroso derivatives − with nitrogen monoxide in the presence and in the absence of dioxygen was studied. The results described here show that tyrosine and naphthols do not undergo nitrosation when they react with ·NO, and so nitrosation of tyrosine in biological systems is highly unlikely. In addition, the oxidation of nitrosonaphthols ←⇄ isonitrosonaphthols by nitric oxide and its derivatives to the corresponding nitro derivatives does not involve the oxoammonium ion, as reported previously. The mechanistic proposals are supported mainly by ESR investigation and electrochemical data. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)" @default.
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- W2023194305 date "2002-12-01" @default.
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- W2023194305 title "On the Role of Nitrogen Monoxide (Nitric Oxide) in the Nitration of a Tyrosine Derivative and Model Compounds" @default.
- W2023194305 doi "https://doi.org/10.1002/1099-0690(200212)2002:23<4011::aid-ejoc4011>3.0.co;2-6" @default.
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