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• W2023199523 abstract "The association of Al(III) with a soil fulvic acid (fua) was monitored in the pH range of 2.5–5.0 by synchronous fluorescence (SyF) spectroscopy. Sets of spectra of 100 mg/l fua solutions obtained at increasing Al(III) concentration (up to about 0.7 mM) at each pH (2.5, 3.0, 3.5, 4.0, 4.5 and 5.0) were preprocessed by the self-modeling mixture analysis method SIMPLISMA, with inverted second derivative spectra in the pure variable selection step, to determine the number and to calculate the spectra and concentration profiles of the components. This procedure detected two major components at all pH values: (i) one shows an increase of fluorescence which corresponds to a fluorescent complex formed between Al(III) and one of the binding sites of the fua; (ii) the other shows a decrease of fluorescence probably due to the decrease of the free concentration of a fluorescent binding site that complexes Al(III) forming a complex that does not show fluorescence." @default.
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• W2023199523 date "1997-08-01" @default.
• W2023199523 modified "2023-10-09" @default.
• W2023199523 title "Study of the interaction of Al(III) with a soil fulvic acid in the acid pH range by self-modeling mixture analysis of synchronous fluorescence spectral data" @default.
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• W2023199523 doi "https://doi.org/10.1016/s0003-2670(97)00275-4" @default.
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