Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023200328> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W2023200328 endingPage "450" @default.
- W2023200328 startingPage "444" @default.
- W2023200328 abstract "Es wird über die Darstellung von Mono-dithiooxalato-bis-phenanthrolinkobalt(III)-Komplexen des Typs [Co(phen)2dto]X (phen = 1,10-Phenanthrolin, dto = Dithiooxalat, X− = Cl, Br, J, NO3, ClO4, H3CCOO) berichtet, deren Eigenschaften im Zusammenhang mit photo- und thermochemischen Untersuchungen an den analogen Oxalato-kobalt(III)-Verbindungen von Interesse sind. Die Kobalt(III)-Komplexe werden komplexchemisch charakterisiert und ihr thermo- und photochemisches Verhalten wird diskutiert. Im Ergebnis der photo- und thermochemischen Untersuchungen ergibt sich für die Photo- und Thermoredoxreaktionen dieser Verbindungen die gleiche Stöchiometrie, wobei COS als Zersetzungsprodukt nachgewiesen werden kann. Der Ablauf der Redoxreaktionen wird charakteristisch vom Anion X− in der zweiten Koordinationssphäre beeinflußt. Dithiooxalate as Thermo-redox and photo-redox Ligand in Bis-phenanthroline-cobalt(III) Complexes The preparation of mono-dithiooxalate-bis-phenanthroline-cobalt(III) complexes of the type [Co(phen)2dto]X (phen = 1.10-phenanthroline, dto = dithiooxalate, X− = Cl, Br, J, NO3 CIO4, H3CCOO) is described. The preparation and investigation of these complexes is of interest in relation with photo- and thermochemical studies of the analogous oxalate-cobalt(III) compounds. The prepared complexes are characterised by their coordination chemical behaviour as well as by thermal and photochemical behaviour. In result of photo- and thermochemical investigations reaction pathways of the thermo and photo reactions can be formulated. COS could be identified as final product of both reactions. The redox reactions are influenced by different anions X− in the second coordination sphere." @default.
- W2023200328 created "2016-06-24" @default.
- W2023200328 creator A5020598133 @default.
- W2023200328 creator A5044319485 @default.
- W2023200328 creator A5048987418 @default.
- W2023200328 creator A5067553852 @default.
- W2023200328 date "1977-01-01" @default.
- W2023200328 modified "2023-10-18" @default.
- W2023200328 title "Dithiooxalat als Thermo- und Photoredoxligand in Bis-phenanthrolin-kobalt(III)-Komplexen" @default.
- W2023200328 cites W2000563893 @default.
- W2023200328 cites W2016090468 @default.
- W2023200328 cites W2019170041 @default.
- W2023200328 cites W2027117217 @default.
- W2023200328 cites W2084568673 @default.
- W2023200328 cites W2090945440 @default.
- W2023200328 cites W2171309564 @default.
- W2023200328 cites W3213204354 @default.
- W2023200328 doi "https://doi.org/10.1002/prac.19773190313" @default.
- W2023200328 hasPublicationYear "1977" @default.
- W2023200328 type Work @default.
- W2023200328 sameAs 2023200328 @default.
- W2023200328 citedByCount "8" @default.
- W2023200328 countsByYear W20232003282021 @default.
- W2023200328 crossrefType "journal-article" @default.
- W2023200328 hasAuthorship W2023200328A5020598133 @default.
- W2023200328 hasAuthorship W2023200328A5044319485 @default.
- W2023200328 hasAuthorship W2023200328A5048987418 @default.
- W2023200328 hasAuthorship W2023200328A5067553852 @default.
- W2023200328 hasConcept C116569031 @default.
- W2023200328 hasConcept C155647269 @default.
- W2023200328 hasConcept C170493617 @default.
- W2023200328 hasConcept C179104552 @default.
- W2023200328 hasConcept C185592680 @default.
- W2023200328 hasConcept C188027245 @default.
- W2023200328 hasConcept C2776351790 @default.
- W2023200328 hasConcept C2777660389 @default.
- W2023200328 hasConcept C515602321 @default.
- W2023200328 hasConcept C55493867 @default.
- W2023200328 hasConcept C55904794 @default.
- W2023200328 hasConcept C71240020 @default.
- W2023200328 hasConcept C8010536 @default.
- W2023200328 hasConceptScore W2023200328C116569031 @default.
- W2023200328 hasConceptScore W2023200328C155647269 @default.
- W2023200328 hasConceptScore W2023200328C170493617 @default.
- W2023200328 hasConceptScore W2023200328C179104552 @default.
- W2023200328 hasConceptScore W2023200328C185592680 @default.
- W2023200328 hasConceptScore W2023200328C188027245 @default.
- W2023200328 hasConceptScore W2023200328C2776351790 @default.
- W2023200328 hasConceptScore W2023200328C2777660389 @default.
- W2023200328 hasConceptScore W2023200328C515602321 @default.
- W2023200328 hasConceptScore W2023200328C55493867 @default.
- W2023200328 hasConceptScore W2023200328C55904794 @default.
- W2023200328 hasConceptScore W2023200328C71240020 @default.
- W2023200328 hasConceptScore W2023200328C8010536 @default.
- W2023200328 hasIssue "3" @default.
- W2023200328 hasLocation W20232003281 @default.
- W2023200328 hasOpenAccess W2023200328 @default.
- W2023200328 hasPrimaryLocation W20232003281 @default.
- W2023200328 hasRelatedWork W1989359163 @default.
- W2023200328 hasRelatedWork W2014815667 @default.
- W2023200328 hasRelatedWork W2021099451 @default.
- W2023200328 hasRelatedWork W2042372453 @default.
- W2023200328 hasRelatedWork W2077818820 @default.
- W2023200328 hasRelatedWork W2098007662 @default.
- W2023200328 hasRelatedWork W2326392555 @default.
- W2023200328 hasRelatedWork W2377396121 @default.
- W2023200328 hasRelatedWork W2620389300 @default.
- W2023200328 hasRelatedWork W4255904581 @default.
- W2023200328 hasVolume "319" @default.
- W2023200328 isParatext "false" @default.
- W2023200328 isRetracted "false" @default.
- W2023200328 magId "2023200328" @default.
- W2023200328 workType "article" @default.