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• W2023202129 abstract "Crystallization velocities in several face-centered-cubic (fcc) and body-centered-cubic (bcc) metals are calculated using molecular dynamics computer simulations for the (1 0 0) and densely packed (1 1 1) or (1 1 0) planar interfaces. We show that the crystallization kinetics can be divided into high- and low-temperature regimes, separated at a crossover temperature, Tc, which is associated with kinetic arrest. In the high-temperature regime, the velocity in both fcc and bcc metals initially increases with the degree of undercooling before reaching a maximum somewhat above the glass temperature. The kinetics is characterized by a thermally activated process. In the low-temperature regime, stresses develop in the interface and reduce the apparent activation energies for interface mobility. For the fcc metals (Cu, Ni, Ag and Pt) the activation energies fall essentially to zero, indicating an athermal process. For bcc metals (Fe, Mo, V, Ta) the activation energies remain finite, varying from ≈0.013 eV (Ta) to ≈0.2 eV (Mo)." @default.
• W2023202129 created "2016-06-24" @default.
• W2023202129 creator A5002422184 @default.
• W2023202129 creator A5069855447 @default.
• W2023202129 date "2010-01-01" @default.
• W2023202129 modified "2023-10-05" @default.
• W2023202129 title "Kinetic stages in the crystallization of deeply undercooled body-centered-cubic and face-centered-cubic metals" @default.
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• W2023202129 doi "https://doi.org/10.1016/j.actamat.2009.09.030" @default.
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