FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023202240> ?p ?o ?g. }

• W2023202240 endingPage "224" @default.
• W2023202240 startingPage "211" @default.
• W2023202240 abstract "The mechanism of “ion-pair” chromatography that employs a non-polar stationary phase and an amphiphilic ion in the eluent to augment the retention of oppositely charged sample components is investigated. Examination of literature data indicates that neither of the simple limiting mechanisms, “ion pairing” or “dynamic ion exchange”, can account for the observed dependence of the retention factor on the concentration of the amphiphilic ion over a sufficiently wide range of conditions. According to the ion-pairing mechanism the analyte traverses the column in the form of an ion pair whereas the dynamic ion-exchange mechanism implies that the interaction of the analyte with the hydrophobic counter-ion adsorbed on the stationary phase surface is responsible for retention. Results of the present study indicate that a mechanistic model based on the assumption that both phenomena take place concurrently does not give adequate agreement with experimental findings either. Therefore, a so-called dynamic complex exchange model is proposed that assumes a metathetical exchange of the analyte between the amphiphilic ion bound to the stationary phase and the ion pairs formed in the mobile phase. Re-examination: of earlier experimental data and the results of computer simulation suggest that this model appropriately reflects the experimentally observed hyperbolic dependence of the retention factor on the concentration of the “ion-pairing” agent as long as the retention-attenuating effect of micelle formation is negligible." @default.
• W2023202240 created "2016-06-24" @default.
• W2023202240 creator A5054919552 @default.
• W2023202240 creator A5074537883 @default.
• W2023202240 date "1980-11-01" @default.
• W2023202240 modified "2023-10-16" @default.
• W2023202240 title "Mechanistic study on ion-pair reversed-phase chromatography" @default.
• W2023202240 cites W1519211433 @default.
• W2023202240 cites W1965685553 @default.
• W2023202240 cites W1971560752 @default.
• W2023202240 cites W1987325353 @default.
• W2023202240 cites W1999869087 @default.
• W2023202240 cites W2002136892 @default.
• W2023202240 cites W2005151074 @default.
• W2023202240 cites W2009354853 @default.
• W2023202240 cites W2020361723 @default.
• W2023202240 cites W2026275324 @default.
• W2023202240 cites W2031935036 @default.
• W2023202240 cites W2033149997 @default.
• W2023202240 cites W2035837509 @default.
• W2023202240 cites W2039108355 @default.
• W2023202240 cites W2039599793 @default.
• W2023202240 cites W2063147688 @default.
• W2023202240 cites W2070057641 @default.
• W2023202240 cites W2075745577 @default.
• W2023202240 doi "https://doi.org/10.1016/s0021-9673(00)83876-5" @default.
• W2023202240 hasPublicationYear "1980" @default.
• W2023202240 type Work @default.
• W2023202240 sameAs 2023202240 @default.
• W2023202240 citedByCount "63" @default.
• W2023202240 countsByYear W20232022402016 @default.
• W2023202240 countsByYear W20232022402017 @default.
• W2023202240 countsByYear W20232022402019 @default.
• W2023202240 countsByYear W20232022402020 @default.
• W2023202240 countsByYear W20232022402022 @default.
• W2023202240 countsByYear W20232022402023 @default.
• W2023202240 crossrefType "journal-article" @default.
• W2023202240 hasAuthorship W2023202240A5054919552 @default.
• W2023202240 hasAuthorship W2023202240A5074537883 @default.
• W2023202240 hasConcept C10390740 @default.
• W2023202240 hasConcept C113196181 @default.
• W2023202240 hasConcept C116817701 @default.
• W2023202240 hasConcept C117760992 @default.
• W2023202240 hasConcept C121332964 @default.
• W2023202240 hasConcept C1276947 @default.
• W2023202240 hasConcept C14103023 @default.
• W2023202240 hasConcept C145148216 @default.
• W2023202240 hasConcept C150394285 @default.
• W2023202240 hasConcept C159467904 @default.
• W2023202240 hasConcept C166361863 @default.
• W2023202240 hasConcept C178790620 @default.
• W2023202240 hasConcept C179998833 @default.
• W2023202240 hasConcept C185592680 @default.
• W2023202240 hasConcept C206967267 @default.
• W2023202240 hasConcept C29705727 @default.
• W2023202240 hasConcept C32909587 @default.
• W2023202240 hasConcept C43617362 @default.
• W2023202240 hasConcept C44280652 @default.
• W2023202240 hasConcept C51724486 @default.
• W2023202240 hasConcept C54101563 @default.
• W2023202240 hasConcept C62520636 @default.
• W2023202240 hasConceptScore W2023202240C10390740 @default.
• W2023202240 hasConceptScore W2023202240C113196181 @default.
• W2023202240 hasConceptScore W2023202240C116817701 @default.
• W2023202240 hasConceptScore W2023202240C117760992 @default.
• W2023202240 hasConceptScore W2023202240C121332964 @default.
• W2023202240 hasConceptScore W2023202240C1276947 @default.
• W2023202240 hasConceptScore W2023202240C14103023 @default.
• W2023202240 hasConceptScore W2023202240C145148216 @default.
• W2023202240 hasConceptScore W2023202240C150394285 @default.
• W2023202240 hasConceptScore W2023202240C159467904 @default.
• W2023202240 hasConceptScore W2023202240C166361863 @default.
• W2023202240 hasConceptScore W2023202240C178790620 @default.
• W2023202240 hasConceptScore W2023202240C179998833 @default.
• W2023202240 hasConceptScore W2023202240C185592680 @default.
• W2023202240 hasConceptScore W2023202240C206967267 @default.
• W2023202240 hasConceptScore W2023202240C29705727 @default.
• W2023202240 hasConceptScore W2023202240C32909587 @default.
• W2023202240 hasConceptScore W2023202240C43617362 @default.
• W2023202240 hasConceptScore W2023202240C44280652 @default.
• W2023202240 hasConceptScore W2023202240C51724486 @default.
• W2023202240 hasConceptScore W2023202240C54101563 @default.
• W2023202240 hasConceptScore W2023202240C62520636 @default.
• W2023202240 hasLocation W20232022401 @default.
• W2023202240 hasOpenAccess W2023202240 @default.
• W2023202240 hasPrimaryLocation W20232022401 @default.
• W2023202240 hasRelatedWork W1506508313 @default.
• W2023202240 hasRelatedWork W1517683124 @default.
• W2023202240 hasRelatedWork W1639290801 @default.
• W2023202240 hasRelatedWork W1964021223 @default.
• W2023202240 hasRelatedWork W1983851953 @default.
• W2023202240 hasRelatedWork W2010730028 @default.
• W2023202240 hasRelatedWork W2036631414 @default.
• W2023202240 hasRelatedWork W2043359868 @default.
• W2023202240 hasRelatedWork W2051989383 @default.
• W2023202240 hasRelatedWork W2363107937 @default.
• W2023202240 hasVolume "201" @default.
• W2023202240 isParatext "false" @default.

• next