Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023203906> ?p ?o ?g. }
- W2023203906 endingPage "235" @default.
- W2023203906 startingPage "227" @default.
- W2023203906 abstract "The hydrolysis of iron(III) was studied in acid aqueous solutions between 25 and 200 °C at saturated water vapour pressure by uv–vis spectrophotometry using a high-temperature, flow-through gold-lined optical cell. The strong ligand-to-metal charge transitions of iron(III) hydroxo complexes at wavelengths below 400 nm were used to obtain molar absorptivities, ε, and equilibrium hydrolysis constants using principal component analysis of the spectra. The total iron(III) concentrations ranged from 6.184 × 10− 5 to 1.652 × 10− 4 mol kg− 1 and the perchloric acid concentration was between 9.31 × 10− 4 and 0.398 mol kg− 1. Under these conditions two iron(III) species were identified, Fe3+ and FeOH2+, and the corresponding hydrolysis constant according to the reactionFe3+ + H2O = FeOH2+ + H+increased from logβ1 = − 2.18 ± 0.01 at 25 °C to 0.54 ± 0.15 at 200 °C. The hydrolysis of Fe3+ to form FeOH2+ is predominantly driven by positive entropy indicating electrostatic interaction between Fe3+ and OH−." @default.
- W2023203906 created "2016-06-24" @default.
- W2023203906 creator A5042295061 @default.
- W2023203906 creator A5079461540 @default.
- W2023203906 date "2008-03-01" @default.
- W2023203906 modified "2023-10-18" @default.
- W2023203906 title "A spectrophotometric study of iron(III) hydrolysis in aqueous solutions to 200 °C" @default.
- W2023203906 cites W1500693158 @default.
- W2023203906 cites W1965034819 @default.
- W2023203906 cites W1965167716 @default.
- W2023203906 cites W1965293989 @default.
- W2023203906 cites W1974579410 @default.
- W2023203906 cites W1975320007 @default.
- W2023203906 cites W1980383266 @default.
- W2023203906 cites W1983168351 @default.
- W2023203906 cites W1987241235 @default.
- W2023203906 cites W1987727701 @default.
- W2023203906 cites W2008555438 @default.
- W2023203906 cites W2009627922 @default.
- W2023203906 cites W2014583614 @default.
- W2023203906 cites W2017489058 @default.
- W2023203906 cites W2018978373 @default.
- W2023203906 cites W2025905379 @default.
- W2023203906 cites W2032137273 @default.
- W2023203906 cites W2033482816 @default.
- W2023203906 cites W2041365504 @default.
- W2023203906 cites W2042149789 @default.
- W2023203906 cites W2043638286 @default.
- W2023203906 cites W2047318161 @default.
- W2023203906 cites W2051719218 @default.
- W2023203906 cites W2065949296 @default.
- W2023203906 cites W2065962147 @default.
- W2023203906 cites W2068714502 @default.
- W2023203906 cites W2069178290 @default.
- W2023203906 cites W2086373855 @default.
- W2023203906 cites W2087375509 @default.
- W2023203906 cites W2088455016 @default.
- W2023203906 cites W2094333778 @default.
- W2023203906 cites W2109750100 @default.
- W2023203906 cites W2146264173 @default.
- W2023203906 cites W2151643323 @default.
- W2023203906 cites W2161321339 @default.
- W2023203906 cites W2170877999 @default.
- W2023203906 cites W2274394856 @default.
- W2023203906 cites W2313844632 @default.
- W2023203906 cites W2893382605 @default.
- W2023203906 cites W2952545291 @default.
- W2023203906 cites W4235040557 @default.
- W2023203906 doi "https://doi.org/10.1016/j.chemgeo.2007.12.006" @default.
- W2023203906 hasPublicationYear "2008" @default.
- W2023203906 type Work @default.
- W2023203906 sameAs 2023203906 @default.
- W2023203906 citedByCount "35" @default.
- W2023203906 countsByYear W20232039062012 @default.
- W2023203906 countsByYear W20232039062013 @default.
- W2023203906 countsByYear W20232039062014 @default.
- W2023203906 countsByYear W20232039062015 @default.
- W2023203906 countsByYear W20232039062016 @default.
- W2023203906 countsByYear W20232039062017 @default.
- W2023203906 countsByYear W20232039062018 @default.
- W2023203906 countsByYear W20232039062019 @default.
- W2023203906 countsByYear W20232039062021 @default.
- W2023203906 countsByYear W20232039062022 @default.
- W2023203906 crossrefType "journal-article" @default.
- W2023203906 hasAuthorship W2023203906A5042295061 @default.
- W2023203906 hasAuthorship W2023203906A5079461540 @default.
- W2023203906 hasConcept C113196181 @default.
- W2023203906 hasConcept C13965031 @default.
- W2023203906 hasConcept C147789679 @default.
- W2023203906 hasConcept C178790620 @default.
- W2023203906 hasConcept C179104552 @default.
- W2023203906 hasConcept C184651966 @default.
- W2023203906 hasConcept C185592680 @default.
- W2023203906 hasConcept C2778161354 @default.
- W2023203906 hasConcept C2780343419 @default.
- W2023203906 hasConcept C43617362 @default.
- W2023203906 hasConcept C544153396 @default.
- W2023203906 hasConcept C94412978 @default.
- W2023203906 hasConceptScore W2023203906C113196181 @default.
- W2023203906 hasConceptScore W2023203906C13965031 @default.
- W2023203906 hasConceptScore W2023203906C147789679 @default.
- W2023203906 hasConceptScore W2023203906C178790620 @default.
- W2023203906 hasConceptScore W2023203906C179104552 @default.
- W2023203906 hasConceptScore W2023203906C184651966 @default.
- W2023203906 hasConceptScore W2023203906C185592680 @default.
- W2023203906 hasConceptScore W2023203906C2778161354 @default.
- W2023203906 hasConceptScore W2023203906C2780343419 @default.
- W2023203906 hasConceptScore W2023203906C43617362 @default.
- W2023203906 hasConceptScore W2023203906C544153396 @default.
- W2023203906 hasConceptScore W2023203906C94412978 @default.
- W2023203906 hasIssue "1-2" @default.
- W2023203906 hasLocation W20232039061 @default.
- W2023203906 hasOpenAccess W2023203906 @default.
- W2023203906 hasPrimaryLocation W20232039061 @default.
- W2023203906 hasRelatedWork W1996549974 @default.
- W2023203906 hasRelatedWork W2006803919 @default.
- W2023203906 hasRelatedWork W2029265473 @default.
- W2023203906 hasRelatedWork W2042932154 @default.