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- W2023204387 abstract "Like the unsubstituted ten-membered ring cis,trans-cyclodeca-1,5-dienes, which are substituted in the 7-, 8- or 9-position, can also be inserted into PdCl2-complexes of the corresponding substituted cis-1,2-divinylcyclohexanes. Mono- or dimethylsubstitution in the 1-, 2-, 6- or 3,4-position makes this induced Cope-rearrangement impossible or more difficult. Wie der unsubstituierte Zehnring lassen sich in 7-, 8- oder 9-Stellung substituierte cis,trans-Cyclodeca-1,5-diene in PdCl2-Komplexe der entsprechend substituierten cis-1,2-Divinylcyclohexane überführen. Mono- oder Dimethylsubstitution in 1-, 2-, 6- oder 3,4-Stellung verhindert oder erschwert diese induzierte Cope-Umlagerung." @default.
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- W2023204387 date "1973-03-01" @default.
- W2023204387 modified "2023-10-03" @default.
- W2023204387 title "PdCl2-induzierte umlagerung substituierter cis,trans-cyclodeca-1,5-diene" @default.
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- W2023204387 doi "https://doi.org/10.1016/s0022-328x(00)84239-4" @default.
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