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- W2023204414 endingPage "1841" @default.
- W2023204414 startingPage "1841" @default.
- W2023204414 abstract "Methods have been described by various authors for monitoring the solvolytic decomposition of the benzenediazonium ion (C6H5N2+) using a UV spectrometer. The benzenediazonium ion decomposes to yield nitrogen gas, which produces bubbles in the reaction mixture. If not immediately expelled from the reaction mixture, these bubbles will alter the effective cell path length and interfere with the UV signal. Within the context of an undergraduate laboratory, this can present a formidable problem. Results of this work show that the reaction can be accurately monitored in real time in an unbuffered solution using a pH electrode, whose signal is virtually unaffected by bubbles in the solution. This article discusses the use of pH electrodes to monitor the aqueous solvolysis of the benzenediazonium ion and shows that the results are in reasonable agreement with literature values." @default.
- W2023204414 created "2016-06-24" @default.
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- W2023204414 date "2005-12-01" @default.
- W2023204414 modified "2023-10-17" @default.
- W2023204414 title "Monitoring the Rate of Solvolytic Decomposition of Benzenediazonium Tetrafluoroborate in Aqueous Media Using a pH Electrode" @default.
- W2023204414 doi "https://doi.org/10.1021/ed082p1841" @default.
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