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- W2023206332 abstract "When the substrate crystal is of a higher symmetry than the crystal of the overgrown film, a finite number of differently oriented island-nuclei (n) develop, which ensues a finite number of misorientations (m) across boundaries in the film where m = C(n,2). This phenomenon of degenerate epitaxy is observed in the double positioning of the [111] f.c.c. metal films on MoS2 with (112) twin boundaries and the triple positioning of the tetragonal YBa2Cu3O7−x (YBCO) on lattice matched cubic SrTiO3 with 90°-boundaries of Σ3. The in situ growth of YBCO films on (001) MgO is a good example of coincidence epitaxy, where the lattice misfit is large. Differently oriented island-nuclei form to minimize interfacial energy by maximizing the lattice coincidence according to the Near Coincidence Site Lattice (NCSL) model and minimizing the misfit and strain energy across the film/substrate interface. Thus the number of possible misorientations (m) from the number of differently oriented island-nuclei (n) is given as m = n2/2 when n is even and m = (n − 1)(n + 1)/4 when n is odd. Only nine misorientations have been observed compared to the calculated value of 64; extensive grain growth and grain annihilation are believed to be responsible for the disappearance of many misorientations. Those [001] tilt boundaries corresponding to Σ5, Σ17, Σ29, off-Σ13 and 45° have all been observed." @default.
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- W2023206332 date "1994-10-01" @default.
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- W2023206332 title "Degenerate epitaxy, coincidence epitaxy and origin of “special” boundaries in thin films" @default.
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- W2023206332 doi "https://doi.org/10.1016/0022-3697(94)90131-7" @default.
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