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• W2023207164 abstract "A single crystal of (±)-[Cuen3]SO4 was studied by MCD and optically between 184° K and 274 ° K. The unique-axis spectra of this crystalline specimen and subsequent moment analysis show that there is (i) an apparent uniaxial ⇄ biaxial phase transition (ca. 180° K); (ii) C-term (C/D = 0.21 BM) behavior of the 16.0 kK band; (iii) vibronic optical intensity behavior of this band with v≅ = 200 cm−1; and (iv) the 8.5 kK band is a genuine electronic transition and not a vibrational overtone. It was also found that [Cuen3]2+ cannot be understood optically by assuming it to be of static D3 symmetry; this infers that the effective symmetry for the electronic events is not D3. A qualitative perturbation model is suggested which accounts for available electronic structural data of [Cuen3]2+ in relation to [Cu(NO2)6]4− and [Cubipy3]2+." @default.
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• W2023207164 date "1976-01-01" @default.
• W2023207164 modified "2023-09-23" @default.
• W2023207164 title "Single crystal properties of [Cuen3]SO4: magnetic CD, optical intensity, and convenient method of following phase transition" @default.
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• W2023207164 doi "https://doi.org/10.1016/s0020-1693(00)95595-6" @default.
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