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- W2023208718 abstract "L'etude de la polycondensation du diglycidyl amino-1-méthyl-2-benzène (commercial et purifié en présence d'amines aromatiques primaire, secondaire et tertiaire) par HPLC, dosage chimique et RMN haute résolution dans les solides (CP MAS) et les liquides (13C et 15N) a permis de connaître la réactivité du groupement N(époxy)-2 et de proposer un mécanisme réactionnel. La comparaison des résultats obtenus sur la résine purifiée et commerciale met en évidence le rôle des impuretés sur la cinétique de réaction et sur la structure du réseau final. The study of the polyaddition of diglycidyl-1-amino-2-methyl benzene (commercial grade and purified in the presence of primary, secondary and tertiary aminobenzenes) by HPLC, chemical measurements, high resolution NMR in the solid (CP MAS) and liquid (13C and 15N) states has allowed the reactivity of the N(epoxy)-2 group to be determined and a reaction mechanism to be proposed. Comparison of results obtained for the commercial grade and purified resins shows the role of impurities on reaction kinetics and on the structure of the final polymer network." @default.
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- W2023208718 date "1984-01-01" @default.
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- W2023208718 title "Résines époxydes—2 Mécanisme réactionnel et cinétique de la réaction du diglycidyl amino-1-méthyl-2-benzène sur les amines aromatiques" @default.
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- W2023208718 doi "https://doi.org/10.1016/0014-3057(84)90179-4" @default.
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