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• W2023210451 abstract "Alkanenitriles having a heteroatom such as nitrogen, oxygen, and sulfur at the γ-position are found to add across alkynes stereo- and regioselectively by nickel/Lewis acid catalysis to give highly substituted acrylonitriles. The heteroatom functionalities likely coordinate to the nickel center to make oxidative addition of the C−CN bonds of the alkyl cyanides kinetically favorable, forming a five-membered nickelacycle intermediate and, thus, preventing β-hydride elimination to allow the alkylcyanation reaction." @default.
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• W2023210451 date "2010-07-01" @default.
• W2023210451 modified "2023-10-16" @default.
• W2023210451 title "Heteroatom-Directed Alkylcyanation of Alkynes" @default.
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• W2023210451 doi "https://doi.org/10.1021/ja1017078" @default.
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