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- W2023211188 abstract "Abstract The synthesis, characterization and reactivity of ytterbium monochloride supported by tridentate Schiff base ligands are described. The metathesis reaction of anhydrous YbCl3 with 1 equivalent of the sodium salt of a Schiff base, [{LNa(THF)}2] (1) [LH = 3,5-But2-2-(OH)-C6H2CH N-8-C9H6N], gave the ytterbium Schiff base monochloride complex L2YbCl (2). Complex 2 reacted with NaOAr (OAr = OC6H3But-2-Me-4) in a 1:1 molar ratio to form the desired aryloxo derivative L2Yb(OAr) (3). Complex 3 can also be prepared by the one-pot reaction of the Schiff base HL, n-BuLi, YbCl3 and NaOAr in a 2:2:1:1 molar ratio. However, an unprecedented ytterbium aryloxide LL′Yb(OAr) (4) (L′ = 3,5-But2-2-(O)C6H2CH(C4H9)-NH-8-C9H6N) can be isolated in low yield as a byproduct in the later case. Reaction of complex 2 with 1 equivalent of (CH2 CH–CH2)MgBr in THF afforded the unexpected complex [Mg(H2N-8-C9H6N)Cl(THF)3]Br (5). Complexes 2–5 were fully characterized by elemental analysis and X-ray diffraction." @default.
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- W2023211188 date "2011-02-01" @default.
- W2023211188 modified "2023-10-15" @default.
- W2023211188 title "Synthesis, reactivity and structural characterization of ytterbium complexes bearing a tridentate [O,N,N] Schiff base ligand" @default.
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- W2023211188 doi "https://doi.org/10.1016/j.poly.2010.09.032" @default.
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