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- W2023216478 abstract "A differential spectrometrical arrangement was used to observe the aggregation of the compounds thymidine-5′-β-(9-acridylamino)-ethyl-phosphate (EAA)pT and 9-β-hydroxyethylaminoacridine (HEAA) (Fig. 1) in aqueous solution. The dimerization constant. Kdi, and the change in the extinction coefficient, Δedi, of both substances were determined over the pH-range from 7 to 12. A significant pH-dependence of Kdi was not observed. The dimerization models for HEAA, two protonation states, and for (EAA)pT, four protonation states, at various pH-values are discussed. This arrangement has proved to be a sensitive method for such kinds of measurement.Eine differentialspektrometrische Anordnung wurde verwendet, um die Assoziationserscheinung der Verbindungen Thymidin-5′-β-(9-acridylamino)-athyl-Phosphat (EAA)pT und 9-(β-Hydroxylathylamino)-Acridin (HEAA) (Fig. 1) in wasriger Losung zu beobachten. Die Dimerisierungskonstante, Kdi, und die Anderung des Extinktionskoeffizienten, Δedi, von beiden Verbindungen wurden uber den pH-Bereich von 7 bis 12 bestimmt. Eine wesentliche pH-Abhangigkeit von Kdi wurde nicht beobachtet. Die Dimerisierungsmodelle fur HEAA mit zwei Protonierungszustanden und fur (EAA)pT mit vier Protonierungszustanden bei verschiedenen pH-Werten sind diskutiert worden. Diese Anordnung hat sich als eine geeignete Methode fur solche Untersuchungen erwiesen." @default.
- W2023216478 created "2016-06-24" @default.
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- W2023216478 date "1979-12-01" @default.
- W2023216478 modified "2023-09-27" @default.
- W2023216478 title "Aggregation of acridine dye and its nucleotide derivative in aqueous solution" @default.
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- W2023216478 doi "https://doi.org/10.1002/bbpc.19790831207" @default.
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