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- W2023221218 abstract "Abstract Reactions of CH 3 [Co] with (CH 3 ) n M (4−n) + (n = 2, 3; M = Sn, Pb) at concentrations high enough to detect (CH 3 ) 4 M in the head space (yields 7.08×10 −5 −2.06×10 −5 %), indicate that dismutation is the major route of production. Similarly, kinetic reactions at lower concentrations show that no demethylation of CH 3 [Co] by (CH 3 ) 3 M + (M = Sn, Pb) occurs after 60 days. From the methylation of SnCl 2 by CH 3 [Co] at pD 1.0 and under aerobic conditions, the following hydrolysis species were observed in the 400 MHz 1 H NMR spectrum: CH 3 - Sn(OH)Cl 2 ·2H 2 O (63.6%), [CH 3 Sn(OH)(H 2 O) 4 ] 2+ (17.6%) and CH 3 Sn(OH) 2 Cl·nH 2 O (18.8%). No methylation products were observed from similar reactions with Pb(II) salts." @default.
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- W2023221218 date "1985-05-01" @default.
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- W2023221218 title "Reactions of methylcobalamin with tin and lead compounds" @default.
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- W2023221218 doi "https://doi.org/10.1016/s0020-1693(00)80687-8" @default.
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