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- W2023223834 abstract "Local atomic structure of KxNa(1−x)NbO3 with 0.0 ≤ x ≤ 1.0 was studied using atomic Pair Distribution Function analysis based on x-ray diffraction. Powdered crystals were found to exhibit a re-entrant behavior by being orthorhombic ( Amm2) for x 0.63. Non-centrosymmetric structure of NaNbO3 ( Amm2) was also evident in the piezoresponse force microscopy analysis revealing the presence of the ferroelectric domains and switching behavior. Lowering of the crystallographic symmetry for 0.42 ≤ x ≤ 0.63 is discussed in terms of differences in the sizes of Na+ and K+ ions and Na–O and K–O bond lengths. Besides being a bridging phase, as suggested by the previous studies on lead-based compositions, present study suggests that lower symmetry monoclinic phase of compositionally disordered perovskite solid solutions could also be a manifestation of the difference in the sizes of constituent ions and bond lengths." @default.
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- W2023223834 date "2014-12-08" @default.
- W2023223834 modified "2023-09-25" @default.
- W2023223834 title "Local atomic structure of KxNa(1−x)NbO3 by total x-ray diffraction" @default.
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- W2023223834 doi "https://doi.org/10.1063/1.4903512" @default.
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