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- W2023224430 abstract "Taylor dispersion is used to measure mutual diffusion coefficients (D) for binary aqueous solutions of sodium hexanoate, heptanoate, octanoate, decanoate, and dodecanoate salts at 25 °C. The diffusion coefficients of sodium hexanoate and heptanoate drop smoothly as the salt concentration is raised. For each of the longer-chain sodium alkanoates, D drops sharply in the region of the critical micelle concentration. Activity coefficient data are used to calculate resistance coefficients from the diffusion results. For aqueous sodium decanoate, micellar aggregation produces a 4-fold decrease in the friction acting on the diffusing salt. The mutual diffusion coefficient of aqueous sodium octanoate is compared with previously reported intradiffusion coefficients for sodium and octanoate ions." @default.
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- W2023224430 date "1996-01-01" @default.
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- W2023224430 title "Mutual Diffusion Coefficients and Resistance Coefficients for Aqueous Solutions of Sodium Alkanoate Surfactants" @default.
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- W2023224430 doi "https://doi.org/10.1021/je950234b" @default.
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