Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023227004> ?p ?o ?g. }
- W2023227004 endingPage "762" @default.
- W2023227004 startingPage "752" @default.
- W2023227004 abstract "We describe a very simple and straightforward strategy towards self-stabilized poly(acrylic acid)-block-poly(butyl acrylate), PAA-b-PBA, block copolymer particles via an ab initio RAFT-controlled emulsion polymerization. Latexes were obtained at 23 wt% solids without the use of additional surfactants, thus avoiding any diffusion issues occurring during film formation. It was possible to reach in a controlled manner PAA-b-PBA diblock copolymers with high molar masses up to 100 kg mol−1. In contrast to previous studies, it was possible to reduce the weight percent of the hydrophilic polymer to 1.2 wt% (with respect to PBA). The block lengths of both PAA and PBA were varied in order to demonstrate the robustness of the system. Ammonium hydroxide was used as a volatile base to adjust the pH of the polymerization medium. Besides improving the polymerization control, ammonium hydroxide is particularly appealing for coating applications, as it can be easily removed during film formation by evaporation. Finally, using these latexes as seeds for the emulsion polymerization of styrene, it was possible to prepare novel nanostructured particles composed of PAA-b-PBA-b-PS triblock copolymers." @default.
- W2023227004 created "2016-06-24" @default.
- W2023227004 creator A5022450184 @default.
- W2023227004 creator A5033424370 @default.
- W2023227004 creator A5057471274 @default.
- W2023227004 date "2013-01-01" @default.
- W2023227004 modified "2023-09-23" @default.
- W2023227004 title "Ab initio RAFT emulsion polymerization of butyl acrylate mediated by poly(acrylic acid) trithiocarbonate" @default.
- W2023227004 cites W1966863664 @default.
- W2023227004 cites W1972038700 @default.
- W2023227004 cites W1975403201 @default.
- W2023227004 cites W1992874055 @default.
- W2023227004 cites W1996433036 @default.
- W2023227004 cites W2001764256 @default.
- W2023227004 cites W2008816032 @default.
- W2023227004 cites W2011519530 @default.
- W2023227004 cites W2020319497 @default.
- W2023227004 cites W2026100316 @default.
- W2023227004 cites W2027521170 @default.
- W2023227004 cites W2029529766 @default.
- W2023227004 cites W2032054527 @default.
- W2023227004 cites W2033500078 @default.
- W2023227004 cites W2036062366 @default.
- W2023227004 cites W2040062577 @default.
- W2023227004 cites W2046639140 @default.
- W2023227004 cites W2056151272 @default.
- W2023227004 cites W2058298740 @default.
- W2023227004 cites W2061554709 @default.
- W2023227004 cites W2066545384 @default.
- W2023227004 cites W2066658415 @default.
- W2023227004 cites W2072024298 @default.
- W2023227004 cites W2077215512 @default.
- W2023227004 cites W2077416001 @default.
- W2023227004 cites W2078992975 @default.
- W2023227004 cites W2086989865 @default.
- W2023227004 cites W2090175782 @default.
- W2023227004 cites W2107066965 @default.
- W2023227004 cites W2123234671 @default.
- W2023227004 cites W2124729238 @default.
- W2023227004 cites W2136118438 @default.
- W2023227004 cites W2144122182 @default.
- W2023227004 cites W2146854707 @default.
- W2023227004 cites W2159719930 @default.
- W2023227004 cites W2160363412 @default.
- W2023227004 cites W2160364838 @default.
- W2023227004 cites W2164168470 @default.
- W2023227004 cites W2167539127 @default.
- W2023227004 cites W2168571305 @default.
- W2023227004 cites W2313504244 @default.
- W2023227004 cites W2320243037 @default.
- W2023227004 cites W329971601 @default.
- W2023227004 doi "https://doi.org/10.1039/c2py20595e" @default.
- W2023227004 hasPublicationYear "2013" @default.
- W2023227004 type Work @default.
- W2023227004 sameAs 2023227004 @default.
- W2023227004 citedByCount "73" @default.
- W2023227004 countsByYear W20232270042013 @default.
- W2023227004 countsByYear W20232270042014 @default.
- W2023227004 countsByYear W20232270042015 @default.
- W2023227004 countsByYear W20232270042016 @default.
- W2023227004 countsByYear W20232270042017 @default.
- W2023227004 countsByYear W20232270042018 @default.
- W2023227004 countsByYear W20232270042019 @default.
- W2023227004 countsByYear W20232270042020 @default.
- W2023227004 countsByYear W20232270042021 @default.
- W2023227004 countsByYear W20232270042022 @default.
- W2023227004 countsByYear W20232270042023 @default.
- W2023227004 crossrefType "journal-article" @default.
- W2023227004 hasAuthorship W2023227004A5022450184 @default.
- W2023227004 hasAuthorship W2023227004A5033424370 @default.
- W2023227004 hasAuthorship W2023227004A5057471274 @default.
- W2023227004 hasConcept C111998727 @default.
- W2023227004 hasConcept C121120078 @default.
- W2023227004 hasConcept C127413603 @default.
- W2023227004 hasConcept C15920480 @default.
- W2023227004 hasConcept C159985019 @default.
- W2023227004 hasConcept C178790620 @default.
- W2023227004 hasConcept C185592680 @default.
- W2023227004 hasConcept C188027245 @default.
- W2023227004 hasConcept C192562407 @default.
- W2023227004 hasConcept C199002037 @default.
- W2023227004 hasConcept C2777566558 @default.
- W2023227004 hasConcept C2777879272 @default.
- W2023227004 hasConcept C2779989194 @default.
- W2023227004 hasConcept C2780076828 @default.
- W2023227004 hasConcept C2780503075 @default.
- W2023227004 hasConcept C34594497 @default.
- W2023227004 hasConcept C42360764 @default.
- W2023227004 hasConcept C44228677 @default.
- W2023227004 hasConcept C521977710 @default.
- W2023227004 hasConceptScore W2023227004C111998727 @default.
- W2023227004 hasConceptScore W2023227004C121120078 @default.
- W2023227004 hasConceptScore W2023227004C127413603 @default.
- W2023227004 hasConceptScore W2023227004C15920480 @default.
- W2023227004 hasConceptScore W2023227004C159985019 @default.
- W2023227004 hasConceptScore W2023227004C178790620 @default.
- W2023227004 hasConceptScore W2023227004C185592680 @default.
- W2023227004 hasConceptScore W2023227004C188027245 @default.