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- W2023227274 abstract "Treatment of RuII(OEP)CO(Py) with Br2 in the presence of excess cyanide leads to oxidative decarbonylation and the formation of the isolable anion [RuIII(OEP)(CN)2]−, from which the neutral complex RuIII(OEP)CN(Py) is readily obtained. [OEP is the dianion of octaethylporphyrin, Py = pyridine.] Reduction of the neutral (cyano)pyridine species in the presence of thiophosgene leads to the formation of RuII(OEP)CS(Py). The spectroscopic and electrochemical properties of the carbonyl and thiocarbonyl compounds within the series M(OEP)CX(Py) (M Fe, Ru, Os; X O, S) are examined and compared. The anionic species [Ru(OEP)CN(L)]− (L CO, Py) are also identified in solution." @default.
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- W2023227274 date "1981-03-01" @default.
- W2023227274 modified "2023-09-24" @default.
- W2023227274 title "Ruthenium porphyrin complexes containing thiocarbonyl or cyanide ligand" @default.
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- W2023227274 doi "https://doi.org/10.1016/s0022-328x(00)82679-0" @default.
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