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- W2023231452 abstract "Abstract Kinetic studies were performed on the polymerization of l-octene with the heterogeneous Ziegler-Natta catalyst systems TiCl4-AlEt3 (I) and TiCl4-AlEt2Br (II). The apparent activation energies determined from Arrhenius plots with catalyst systems I and II are 37.62 and 44.03 kJ/mol, respectively. The rate of polymerization was found to be proportional to the catalyst and monomer concentrations. A two-step coordinate anionic mechanism involving competitive adsorption between the monomer and the cocatalyst on the catalyst surface (Langmuir-Hinshel-wood model) was proposed based on the dependence of the rate on the cocatalyst concentration. The polymers were characterized by IR, 1H-NMR, and 13C-NMR spectroscopy." @default.
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- W2023231452 title "Kinetics of Polymerization of 1-Octene with the Catalyst Systems Ticl4-Alet3or Alet2Br" @default.
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- W2023231452 doi "https://doi.org/10.1080/10601329409351527" @default.
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