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• W2023231668 abstract "Compared to similar catalysts dissolved in solution, electrolysis using a cobalt complex chemisorbed onto nanocrystalline titanium dioxide cathodes was catalytically more efficient in a microemulsion for the debromination of dibromocyclohexane, and the stereoselective cyclization of 2-(4-bromobutyl)-2-cylohexen-1-one to 1-decalone. 1,2-Dibromocyclohexane was converted to cyclohexene with 100 h-1 turnover using TiO2 electrodes coated with vitamin B12 hexacarboxylate. This represented a 5-fold increase in the turnover number compared to the same reaction catalyzed using vitamin B12 in solution on a bare carbon electrode. Cyclization of 2-(4-bromobutyl)-2-cyclohexen-1-one in the microemulsion gave similar trans:cis ratios (14−18) for product 1-decalone for both soluble and adsorbed catalyst systems, but more than 100-fold larger turnover number using the coated TiO2 electrodes. In DMF, the coated TiO2 gives little stereoselectivity for this reaction, and poorer turnover than that in the microemulsion. Binding vitamin B12 hexacarboxylate onto TiO2 electrodes improves electron-transfer rates and catalytic efficiency while retaining essential features of cobalt complex-mediated catalysis in microemulsions." @default.
• W2023231668 created "2016-06-24" @default.
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• W2023231668 date "1998-10-29" @default.
• W2023231668 modified "2023-10-11" @default.
• W2023231668 title "Catalytic Electrochemical Synthesis Using Nanocrystalline Titanium Dioxide Cathodes in Microemulsions" @default.
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• W2023231668 doi "https://doi.org/10.1021/la9804536" @default.
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