Matches in SemOpenAlex for { <https://semopenalex.org/work/W2023233417> ?p ?o ?g. }
- W2023233417 endingPage "123" @default.
- W2023233417 startingPage "107" @default.
- W2023233417 abstract "Immobilization on silica of selective homogeneous hydroformylation catalysts based on xanthene ligands is reviewed. Various immobilized catalysts are compared, such as SAPC, sol–gel-based catalysts, silica-anchored catalysts used both in an organic phase as well as in supercritical carbon dioxide (scCO2), and chemical modifications of silica-anchored catalysts. In all instances, the high selectivity of the homogeneous Xantphos ligands is retained and linear to branched ratios are 20 or higher. Formation of 2-octene from 1-octene via isomerization also remains low (<5%) as in the homogeneous phase. The rates expressed in turnover frequencies drop considerably except for the experiments in scCO2, which are only half of those in the homogeneous phase. Leaching of rhodium to the product is in all cases below the detection limit of ICP-AES (1 ppm)." @default.
- W2023233417 created "2016-06-24" @default.
- W2023233417 creator A5005138503 @default.
- W2023233417 creator A5013850715 @default.
- W2023233417 creator A5030930015 @default.
- W2023233417 creator A5070975248 @default.
- W2023233417 date "2002-05-01" @default.
- W2023233417 modified "2023-10-17" @default.
- W2023233417 title "Xantphos-based, silica-supported, selective, and recyclable hydroformylation catalysts: a review" @default.
- W2023233417 cites W1015969496 @default.
- W2023233417 cites W13915815 @default.
- W2023233417 cites W1568644365 @default.
- W2023233417 cites W1631259664 @default.
- W2023233417 cites W1967160425 @default.
- W2023233417 cites W1967277001 @default.
- W2023233417 cites W1968704943 @default.
- W2023233417 cites W1975856555 @default.
- W2023233417 cites W1976225098 @default.
- W2023233417 cites W1982699725 @default.
- W2023233417 cites W1984163070 @default.
- W2023233417 cites W1985713568 @default.
- W2023233417 cites W1986372915 @default.
- W2023233417 cites W1986753208 @default.
- W2023233417 cites W1989549118 @default.
- W2023233417 cites W1992038544 @default.
- W2023233417 cites W1994941612 @default.
- W2023233417 cites W1997498238 @default.
- W2023233417 cites W1998887971 @default.
- W2023233417 cites W2003562330 @default.
- W2023233417 cites W2008809271 @default.
- W2023233417 cites W2010676355 @default.
- W2023233417 cites W2013549550 @default.
- W2023233417 cites W2017139429 @default.
- W2023233417 cites W2017681223 @default.
- W2023233417 cites W2034300556 @default.
- W2023233417 cites W2038836357 @default.
- W2023233417 cites W2040587278 @default.
- W2023233417 cites W2045950415 @default.
- W2023233417 cites W2046797660 @default.
- W2023233417 cites W2055137998 @default.
- W2023233417 cites W2060105922 @default.
- W2023233417 cites W2060475920 @default.
- W2023233417 cites W2065342383 @default.
- W2023233417 cites W2071346502 @default.
- W2023233417 cites W2072483750 @default.
- W2023233417 cites W2074474157 @default.
- W2023233417 cites W2076721281 @default.
- W2023233417 cites W2082340530 @default.
- W2023233417 cites W2083580176 @default.
- W2023233417 cites W2083770823 @default.
- W2023233417 cites W2085553155 @default.
- W2023233417 cites W2087947900 @default.
- W2023233417 cites W2088115176 @default.
- W2023233417 cites W2095524926 @default.
- W2023233417 cites W2100309578 @default.
- W2023233417 cites W2107303968 @default.
- W2023233417 cites W2107716124 @default.
- W2023233417 cites W2125160925 @default.
- W2023233417 cites W2129532734 @default.
- W2023233417 cites W2137265130 @default.
- W2023233417 cites W2138327642 @default.
- W2023233417 cites W2142406538 @default.
- W2023233417 cites W2154626584 @default.
- W2023233417 cites W2165560049 @default.
- W2023233417 cites W2493203190 @default.
- W2023233417 cites W2949532579 @default.
- W2023233417 cites W2952181303 @default.
- W2023233417 cites W4233893028 @default.
- W2023233417 cites W84364293 @default.
- W2023233417 doi "https://doi.org/10.1016/s1381-1169(01)00504-0" @default.
- W2023233417 hasPublicationYear "2002" @default.
- W2023233417 type Work @default.
- W2023233417 sameAs 2023233417 @default.
- W2023233417 citedByCount "43" @default.
- W2023233417 countsByYear W20232334172012 @default.
- W2023233417 countsByYear W20232334172013 @default.
- W2023233417 countsByYear W20232334172014 @default.
- W2023233417 countsByYear W20232334172017 @default.
- W2023233417 countsByYear W20232334172020 @default.
- W2023233417 countsByYear W20232334172022 @default.
- W2023233417 countsByYear W20232334172023 @default.
- W2023233417 crossrefType "journal-article" @default.
- W2023233417 hasAuthorship W2023233417A5005138503 @default.
- W2023233417 hasAuthorship W2023233417A5013850715 @default.
- W2023233417 hasAuthorship W2023233417A5030930015 @default.
- W2023233417 hasAuthorship W2023233417A5070975248 @default.
- W2023233417 hasConcept C100805817 @default.
- W2023233417 hasConcept C118792377 @default.
- W2023233417 hasConcept C126661725 @default.
- W2023233417 hasConcept C127413603 @default.
- W2023233417 hasConcept C161790260 @default.
- W2023233417 hasConcept C178790620 @default.
- W2023233417 hasConcept C185592680 @default.
- W2023233417 hasConcept C2778499101 @default.
- W2023233417 hasConcept C42360764 @default.
- W2023233417 hasConcept C502130503 @default.
- W2023233417 hasConcept C521398313 @default.
- W2023233417 hasConceptScore W2023233417C100805817 @default.